Highly efficient atom transfer radical addition reactions with a RuIII complex as a catalyst precursor

被引：113

作者：

Quebatte, Laurent ^{[1
]}

Thommes, Katrin ^{[1
]}

Severin, Kay ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 23期

关键词：

D O I：

10.1021/ja0617542

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of the air-stable RuIII complex [Cp*RuCl2(PPh3)] with AIBN can be used to catalyze the atom transfer radical addition reactions of polychlorinated compounds and of sulfonyl chlorides to olefins with unprecedented turnover numbers of up to 44000. Copyright © 2006 American Chemical Society.

引用

页码：7440 / 7441

页数：2

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