A study by emission spectroscopy of the N-2 active species in pulsed DC discharges

被引:41
作者
Bruhl, SP [1 ]
Russell, MW [1 ]
Gomez, BJ [1 ]
Grigioni, GM [1 ]
Feugeas, JN [1 ]
Ricard, A [1 ]
机构
[1] UNIV TOULOUSE 3,CPAT,F-31062 TOULOUSE,FRANCE
关键词
D O I
10.1088/0022-3727/30/21/002
中图分类号
O59 [应用物理学];
学科分类号
摘要
From the optical emission of N-2 and N-2(+) radiative states in the negative glow of N-2 DC pulsed discharges at pressures 1-4 Torr (133-532 Pa) and current densities 1-6 mA cm(-2), it has been determined that the vibrational excitation of the N-2 state deviates from a Boltzmann distribution and strong intensities of the N-2 second positive system (especially from v = 1) were also observed in the afterglow. Such strong emission is interpreted in terms of the growing of the N-2(X, v) vibrational distribution in the post-discharge region as the gas temperature is reduced. The N-2(+)(B-2 Sigma(u)(+)) states are mainly produced by electron collisions on N-2(+)(X) ions under discharge conditions and quickly disappear in the afterglow as a result of N-2(+)-electron recombination.
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页码:2917 / 2922
页数:6
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