Single-crystal EPR studies of a spin-frustrated imidazolate-bridged trinuclear copper(II) complex

被引：40

作者：

Padilla, J

Gatteschi, D

Chaudhuri, P

机构：

[1] UNIV FLORENCE,DEPT CHEM,I-50144 FLORENCE,ITALY

[2] MAX PLANCK INST STRAHLENCHEM,D-45470 MULHEIM,GERMANY

来源：

INORGANICA CHIMICA ACTA | 1997年 / 260卷 / 02期

关键词：

EPR; spin-frustration; imidazolate; trimer; copper(II);

D O I：

10.1016/S0020-1693(96)05548-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The single-crystal and polycrystalline powder EPR spectra of the trinuclear compound [L3Cu3(Im)(3)](ClO4)(3), L=1,4.7-trimethyl-1,4,7-triazacyclononane, and Im = imidazolate, have been measured in the temperature range 4.2-300 K. The spectra are explained based on the spin-frustration, the low symmetry, and the intercluster exchange interactions.

引用

页码：217 / 220

页数：4

共 15 条

[1]

[Anonymous], 1982, TRANSIT METAL CHEM

[2] ELECTRON-PARAMAGNETIC-RES SPECTRA OF TRINUCLEAR COMPLEXES - OCTACHLORODIADENINIUMTRICOPPER(II) TETRAHYDRATE [J].