Regiospecific high yield reductive coupling of diynes to give a luminescent rhodium complex

被引：38

作者：

Rourke, JP ^{[1
]}

Batsanov, AS

Howard, JAK

Marder, TB

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[2] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 24期

关键词：

D O I：

10.1039/b108625a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 2 equivalents of 1,4-bis(p-tolylethynyl)buta-1,3-diyne with [(PMe3)(4)Rh(-C equivalent to CSiMe3)] gives the unusual, highly luminescent mer, cis-[tris(trimethylphosphine)trimethylsilylethynyl-2,5-bis(p-tolylethynyl)-3,4-bis(p-tolyl)rhodacyclopenta-2,4-diene] 5 in quantitative yield which has been fully characterised by H-1 and P-31{H-1} NMR, IR, UV-VIS and luminescence spectroscopies, elemental analysis and single crystal X-ray diffraction.

引用

页码：2626 / 2627

页数：2

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