Ligand reorganization energies as a basis for the design of synergistic metal ion extraction systems

被引：37

作者：

Dietz, ML

Bond, AH

Hay, BP

Chiarizia, R

Huber, VJ

Herlinger, AW

机构：

[1] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA

[2] Pacific NW Lab, Environm Mol Sci Lab, Richland, WA 99352 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 13期

关键词：

D O I：

10.1039/a902842k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the extraction of alkaline earth cations by acidic organophosphorus extractants, a correlation has been demonstrated between the effectiveness of the stereoisomers of dicyclohexano-18-crown-6 as synergists and the strain energy associated with conversion of the unbound crown ether to its complexed form.

引用

页码：1177 / 1178

页数：2