Crystal structure determination of 4f-5f heterometallic complexes

被引：22

作者：

Leverd, PC ^{[1
]}

Rinaldo, D ^{[1
]}

Nierlich, M ^{[1
]}

机构：

[1] CEA Saclay, Serv Chim Mol, F-91191 Gif Sur Yvette, France

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 06期

关键词：

D O I：

10.1039/b200199n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [UO2Cl4](2-) with tBu-calix[6] arene (H6L) in the presence of lanthanum triflate in pyridine leads to the formation of [U{(H2L)LaCl2(NC5H5)(4)}(2)] (1); in the course of the reaction, the uranyl cations (UO22+) are transformed into U(+VI) alkoxides (1) and "UO6" oxides at the centre of the decametallic cluster [ULa9O8Cl15(O3SCF3)(6)(NC5H5)(9)](4-) (2); complexes 1 and 2 are the first 4f-5f heterometallic complexes to be reported.

引用

页码：829 / 831

页数：3

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