trans-Tetracarbonylbis(tri-tert-butyl-phosphite)molybdenum(0)

被引：3

作者：

Alyea, EC

Ferguson, G

Song, SQ

机构：

[1] Dept. of Chemistry and Biochemistry, University of Guelph, Guelph

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195007803

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Mo atom in the title compound, [MO(CO)(4)(C12H27O3P)(2)], lies on an inversion centre and has slightly distorted octahedral geometry, with principal dimensions Mo-P 2.4699 (7), Mo-C 2.027 (4), 2.031 (3) Angstrom, P-Mo-P 180, cis-C-Mo-C 88.7 (2), C-Mo-P 86.12 (10) and 87.27 (9)degrees. The geometry about the P atom is distorted from tetrahedral, with Mo-P-O angles in the range 108.04 (9)-126.03 (10)degrees and reduced O-P-O angles in the range 96.71 (13)-106.09 (14)degrees. The average cone angle for the tert-butyl phosphite ligand is 156 degrees.

引用

页码：66 / 69

页数：4