Synthesis and properties of poly [3-(ω-bromoalkyl)thiophene]

被引：9

作者：

Pomerantz, M ^{[1
]}

Liu, MLX ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Ctr Adv Polymer Res, Arlington, TX 76019 USA

来源：

SYNTHETIC METALS | 1999年 / 101卷 / 1-3期

关键词：

polythiophene and derivatives; semiconducting films; substitution reactions; UV-vis absorption;

D O I：

10.1016/S0379-6779(98)01219-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Bromine functionalized polymers, poly[3-(6-bromohexyl)thiophene] (PBrHT) and poly[3-(12-bromododecyl)thiophene] (PBrDT) were synthesized by FeCl3 oxidation of the corresponding monomers. Substitution of bromine by iodide in PBrHT resulted in poly[3-(6-iodohexyl)thiophene] with 97% of bromine displacement by iodide. Molecular weight, conductivity, NMR, UV-vis and fluorescence spectra of PBrHT and PBrDT were obtained.

引用

页码：95 / 95

页数：1

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