Palladium nanoparticles entrapped in heavily fluorinated compounds

被引：39

作者：

Tristany, M

Courmarcel, J

Dieudonné, P

Moreno-Mañas, M

Pleixats, R

Rimola, A

Sodupe, M

Villarroya, S

机构：

[1] Univ Autonoma Barcelona, Dept Chem, E-08193 Barcelona, Spain

[2] Univ Montpellier 2, CNRS, Lab Colloides Verres & Nanomat, UMR 5587, Montpellier, France

来源：

CHEMISTRY OF MATERIALS | 2006年 / 18卷 / 03期

关键词：

D O I：

10.1021/cm051967a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Palladium nanoparticles formed by the reduction of palladium(II) chloride with methanol or 2-propanol are stabilized by entrapment in solid heavily fluorinated compounds, as suggested by powder X-ray diffraction. Some of the stabilizers are fluorohydrocarbons without a functional group. Calculations suggest that minor amounts of Pd(II) on the surface of the nanoparticles might be the origin of attractive interactions with the negative periphery of perfluorinated chains (CnF2n+1). The role of sodium acetate in the precipitation of nanoparticles is underlined.

引用

页码：716 / 722

页数：7

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[41]

2-J

[42] Reduced transition metal colloids: A novel family of reusable catalysts? [J].