Cyanide: A Strong-Field Ligand for Ferrohemes and Hemoproteins?

被引：39

作者：

Li, Jianfeng ^{[1
]}

Lord, Richard L. ^{[2
]}

Noll, Bruce C. ^{[1
]}

Baik, Mu-Hyun ^{[2
]}

Schulz, Charles E. ^{[3
]}

Scheidt, W. Robert ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

[2] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[3] Knox Coll, Dept Phys, Galesburg, IL USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 52期

基金：

美国国家卫生研究院;

关键词：

cyanides; iron; magnetic properties; porphyrinoids; spin crossover;

D O I：

10.1002/anie.200804116

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) A CN weakling? The cyanide ligand in the five-coordinate iron(II) porphyrinate complex [Fe(tpp) (CN)]- (tpp= tetraphenylporphinato) is not a sufficiently strong-field ligand to cause the complex to be in the low-spin state under all conditions. Rather, the complex displays a reversible low-spin (LS) to high-spin (HS) crossover with no hysteresis. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：10144 / 10146

页数：3

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