Stereoselective synthesis and use in catalytic asymmetric addition of diethylzinc to benzaldehyde of new chiral amino alcohol complexes: Influence of the chromium complexation on the enantioselectivity

被引：26

作者：

Malfait, S ^{[1
]}

Pelinski, L ^{[1
]}

Brocard, J ^{[1
]}

机构：

[1] UNIV LILLE 1,CATALYSE HETEROGENE & HOMOGENE LAB,GRP SYNTH ORGANOMET,URA CNRS 402,F-59655 VILLENEUVE DASCQ,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 03期

关键词：

D O I：

10.1016/0957-4166(96)00056-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The optically active amino alcohol (arene)chromium (+)-(S,1S)-3-6 complexes were synthesized from enantiomerically pure indanone complex. As well as their uncomplexed counterparts, they have been used as chiral catalysts in the asymmetric addition of diethylzinc to benzaldehyde: 1-Phenylpropanol has obtained in up to 70% enantiomeric excess. A beneficial effect of the tricarbonyl chromium tripod on the enantioselectivity has been shown. (C) 1996 Elsevier Science Ltd

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页码：653 / 656

页数：4

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