A zwitterionic palladium(II) η3-boratoxypentadienyl complex:: Cooperative activation of dibenzylideneacetone between palladium and a phosphine/thioether/borane ligand

被引：50

作者：

Emslie, David J. H. ^{[1
]}

Blackwell, James. M. ^{[1
]}

Britten, James F. ^{[1
]}

Harrington, Laura E. ^{[1
]}

机构：

[1] McMaster Univ, Dept Chem, Hamilton, ON L8S 4M1, Canada

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 10期

关键词：

D O I：

10.1021/om0602052

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A free phosphine/thioether/borane ligand (5) suitable to position a Lewis acidic borane in close proximity to a coordinated late transition metal has been prepared. Reaction with 0.5 [Pd-2(dba)(3)] gave a zwitterionic palladium(II) eta(3)- boratoxypentadienyl complex with the empirical formula [Pd(dba)(5)].

引用

页码：2412 / 2414

页数：3

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