Synthesis of iron-nickel nanoparticles via a nonaqueous organometallic route

被引：65

作者：

Chen, Yuanzhi ^{[1
]}

Luo, Xiaohua ^{[1
]}

Yue, Guang-Hui ^{[1
]}

Luo, Xuetao ^{[1
]}

Peng, Dong-Liang ^{[1
]}

机构：

[1] Xiamen Univ, Dept Mat Sci & Engn, Coll Mat, Res Ctr Mat Design & Applicat, Xiamen 361005, Peoples R China

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2009年 / 113卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Iron-nickel; Nanoparticle; Chemical synthesis; Magnetic properties; FE-NI ALLOYS; MAGNETIC-PROPERTIES; ULTRAFINE PARTICLES; SIZE; REDUCTION; CHLORIDES;

D O I：

10.1016/j.matchemphys.2008.07.118

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Fe-Ni nanoparticles have been synthesized via a nonaqueous solution-phase approach using thermal decomposition of Ni(II) acetylacetonate and Fe(III) acetylacetonate in oleylamine without further reducing agents. The analyses of powder X-ray diffraction and transmission electron microscopy show that the as-synthesized Fe-Ni nanoparticles possess a face-centered cubic (fcc) crystalline structure and exhibit a polydispersed characteristic. The particle morphology and size distribution can be further controlled by introducing surfactants in the reaction system, and the final chemical composition also can be tuned to some extent by varying the initial molar ratios of metal precursors. Room temperature magnetic measurements reveal a ferromagnetic characteristic for the as-synthesized nanoparticles. An increased saturation magnetization has been observed with increasing Fe contents. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：412 / 416

页数：5

共 22 条

[21] Solution phase reduction to Fe-Ni alloy nanostructures with tunable shape and size [J].