Selective 6-endo cyclization of the acyl radicals onto the nitrogen of imine and oxazoline C-N bonds

被引：59

作者：

Tojino, Mami ^{[1
]}

Otsuka, Noboru ^{[1
]}

Fukuyama, Takahide ^{[1
]}

Matsubara, Hiroshi ^{[1
]}

Ryu, Ilhyong ^{[1
]}

机构：

[1] Osaka Prefecture Univ, Grad Sch Sci, Dept Chem, Osaka 5998531, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 24期

关键词：

D O I：

10.1021/ja0623865

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acyl radicals generated by the addition of alkyl or vinyl radicals to carbon monoxide cyclized onto the C-N bonds of imines and oxazoline with perfect 6-endo selectivity, driven by a preference for attack at nitrogen. Copyright © 2006 American Chemical Society.

引用

页码：7712 / 7713

页数：2

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