Synthesis of all-silica and high-silica molecular sieves in fluoride media

被引:329
作者
Camblor, MA [1 ]
Villaescusa, LA [1 ]
Díaz-Cabañas, MJ [1 ]
机构
[1] Inst Tecnol Quim, Valencia 46022, Spain
关键词
synthesis; silica zeolites; framework density; phase selectivity; connectivity defects;
D O I
10.1023/A:1019154304344
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Recent advances in the synthesis of all-silica and high-silica crystalline molecular sieves in fluoride media, with special regard to low framework density phases, are presented. The fundamental differences between the synthesis in hydroxide and fluoride media with respect to the properties of the materials obtained and the phase selectivity of the crystallization are discussed.
引用
收藏
页码:59 / 76
页数:18
相关论文
共 73 条
[51]  
MENTZEN BF, 1991, CR ACAD SCI II, V313, P177
[52]   LAYERED STRUCTURE OF ERB-1 MICROPOROUS BOROSILICATE PRECURSOR AND ITS INTERCALATION PROPERTIES TOWARDS POLAR-MOLECULES [J].
MILLINI, R ;
PEREGO, G ;
PARKER, WO ;
BELLUSSI, G ;
CARLUCCIO, L .
MICROPOROUS MATERIALS, 1995, 4 (2-3) :221-230
[53]   Guest/host relationships in zeolite synthesis: ring-substituted piperidines and the remarkable adamantane mimicry by 1-azonio spiro [5.5] undecanes [J].
Nakagawa, Y ;
Lee, GS ;
Harris, TV ;
Yuen, LT ;
Zones, SI .
MICROPOROUS AND MESOPOROUS MATERIALS, 1998, 22 (1-3) :69-85
[54]  
NAKAGAWA Y, 1993, Patent No. 5268161
[55]   THERMOCHEMICAL STUDY OF THE STABILITY OF FRAMEWORKS IN HIGH-SILICA ZEOLITES [J].
PETROVIC, I ;
NAVROTSKY, A ;
DAVIS, ME ;
ZONES, SI .
CHEMISTRY OF MATERIALS, 1993, 5 (12) :1805-1813
[56]   CRYSTAL-STRUCTURE OF TETRAPROPYLAMMONIUM FLUORIDE CONTAINING PRECURSOR TO FLUORIDE SILICALITE [J].
PRICE, GD ;
PLUTH, JJ ;
SMITH, JV ;
BENNETT, JM ;
PATTON, RL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (22) :5971-5977
[57]  
RAO PRH, 1998, P 12 INT ZEOL C, P1515
[58]  
Roth WJ, 1995, STUD SURF SCI CATAL, V94, P301
[59]  
SAXTON RJ, 1995, Patent No. 5453511
[60]   Hydrophobic properties of all-silica zeolite beta [J].
Stelzer, J ;
Paulus, M ;
Hunger, M ;
Weitkamp, J .
MICROPOROUS AND MESOPOROUS MATERIALS, 1998, 22 (1-3) :1-8