(Bromodimethyl) sulfonium bromide: An efficient catalyst for solvent-free synthesis of 1,5-benzodiazepines

被引：22

作者：

Das, B ^{[1
]}

Ramu, R ^{[1
]}

Ravikanth, B ^{[1
]}

Reddy, VS ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2006年 / 246卷 / 1-2期

关键词：

1,5-benzodiazepine; o-phenylenediamine; ketone; (bromodimethyl) sulfonium bromide; new catalyst; solvent-free conditions;

D O I：

10.1016/j.molcata.2005.10.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An efficient solvent-free synthesis of 1,5-benzodiazepines by condensation of o-phenylenediamines with ketones in the presence of catalytic amount of (bromodimethyl) sulfonium bromide has been accomplished. The condensation occurred at room temperature and the products were formed in high yields. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：76 / 78

页数：3

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