Base-promoted benzene C-H activation chemistry at an amido pincer complex of platinum(II)

被引：63

作者：

Harkins, SB ^{[1
]}

Peters, JC ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Arnold & Mabel Beckman Labs Chem Synthesis, Pasadena, CA 91125 USA

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 09期

关键词：

D O I：

10.1021/om011044z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermally robust platinum(11) complex (BQA)Pt(OTf) undergoes benzene C-H bond activation at 150 degreesC but requires the presence of (NPr2Et)-Pr-i. The reaction products are the phenyl complex (BQA)Pt(Ph) and a stoichiometric equivalent of [(HNPr2Et)-Pr-i][OTf].

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页码：1753 / 1755

页数：3

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