Studies on microgels .3. Synthesis using living free radical polymerization

被引：87

作者：

Abrol, S ^{[1
]}

Kambouris, PA ^{[1
]}

Looney, MG ^{[1
]}

Solomon, DH ^{[1
]}

机构：

[1] UNIV MELBOURNE,DEPT CHEM ENGN,POLYMER SCI GRP,PARKVILLE,VIC 3052,AUSTRALIA

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1997年 / 18卷 / 09期

关键词：

D O I：

10.1002/marc.1997.030180901

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Microgels which are soluble crosslinked polymer networks have been prepared using the nitroxide living free radical polymerization methodology. When heated in the pre sence of tert-butylstyrene and 1,4-divinylbenzene, the alkoxyamine 1 derived from 2,2'-azoisobutyronitrile (AIBN) afforded a high molecular weight soluble polymer which was shown by size exclusion chromatography in conjunction with an on-line multi angle laser light scattering (MALLS) detector to have microgel properties.

引用

页码：755 / 760

页数：6

共 21 条

[1] MICROGELS - POLYMERS WITH A SPECIAL MOLECULAR ARCHITECTURE
ANTONIETTI, M
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (12): : 1743 - 1747
[2] PROPERTIES OF FRACTAL DIVINYLBENZENE MICROGELS
ANTONIETTI, M
ROSENAUER, C
[J]. MACROMOLECULES, 1991, 24 (11) : 3434 - 3442
[3] Boggs LJ, 1996, J COATING TECHNOL, V68, P63
[4] Well-defined block copolymers comprising styrene acrylonitrile random copolymer sequences synthesized by ''living'' radical polymerization
Fukuda, T
Terauchi, T
Goto, A
Tsujii, Y
Miyamoto, T
[J]. MACROMOLECULES, 1996, 29 (08) : 3050 - 3052
[5] NARROW MOLECULAR-WEIGHT RESINS BY A FREE-RADICAL POLYMERIZATION PROCESS
GEORGES, MK
VEREGIN, RPN
KAZMAIER, PM
HAMER, GK
[J]. MACROMOLECULES, 1993, 26 (11) : 2987 - 2988
[6] MICROGELS .1. SOLUTION POLYMERIZATION USING VINYL MONOMERS
GRAHAM, NB
HAYES, CMG
[J]. MACROMOLECULAR SYMPOSIA, 1995, 93 : 293 - 300
[7] QUANTITATIVE STUDIES ON FREE-RADICAL REACTIONS WITH THE SCAVENGER 1,1,3,3-TETRAMETHYLISOINDOLINYL-2-OXY
GRIFFITHS, PG
RIZZARDO, E
SOLOMON, DH
[J]. TETRAHEDRON LETTERS, 1982, 23 (12) : 1309 - 1312
[8] Well-defined random copolymers by a ''living'' free-radical polymerization process
Hawker, CJ
Elce, E
Dao, JL
Volksen, W
Russell, TP
Barclay, GG
[J]. MACROMOLECULES, 1996, 29 (07) : 2686 - 2688
[9] ACCURATE CONTROL OF CHAIN-ENDS BY A NOVEL LIVING FREE-RADICAL POLYMERIZATION PROCESS
HAWKER, CJ
HEDRICK, JL
[J]. MACROMOLECULES, 1995, 28 (08) : 2993 - 2995
[10] MOLECULAR-WEIGHT CONTROL BY A LIVING FREE-RADICAL POLYMERIZATION PROCESS
HAWKER, CJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (24) : 11185 - 11186

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