Studies on microgels .3. Synthesis using living free radical polymerization

被引：87

作者：

Abrol, S ^{[1
]}

Kambouris, PA ^{[1
]}

Looney, MG ^{[1
]}

Solomon, DH ^{[1
]}

机构：

[1] UNIV MELBOURNE,DEPT CHEM ENGN,POLYMER SCI GRP,PARKVILLE,VIC 3052,AUSTRALIA

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1997年 / 18卷 / 09期

关键词：

D O I：

10.1002/marc.1997.030180901

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Microgels which are soluble crosslinked polymer networks have been prepared using the nitroxide living free radical polymerization methodology. When heated in the pre sence of tert-butylstyrene and 1,4-divinylbenzene, the alkoxyamine 1 derived from 2,2'-azoisobutyronitrile (AIBN) afforded a high molecular weight soluble polymer which was shown by size exclusion chromatography in conjunction with an on-line multi angle laser light scattering (MALLS) detector to have microgel properties.

引用

页码：755 / 760

页数：6

共 21 条

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