Synthesis of the rhenium allyl chloride complex Cp*Re(eta(3)-C3H5)(CO)Cl and reactions to give hydride, phenyl and alkyl derivatives

被引：3

作者：

He, YX ^{[1
]}

Sutton, D ^{[1
]}

机构：

[1] SIMON FRASER UNIV,DEPT CHEM,BURNABY,BC V5A 1S6,CANADA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 538卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会;

关键词：

rhenium; allyl; synthesis; cyclopentadienyl; hydride; chloride;

D O I：

10.1016/S0022-328X(96)06897-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The rhenium eta(3)-allyl chloro complex Cp*Re(eta(3)-C3H5)(CO)Cl (5) has been synthesized from the photolysis of Cp*Re(CO)(3) and allyl chloride, or from the reaction of the cationic complex [Cp* Re(eta(3)-C3H5)(CO)(2)](+) with PhIO and Me4NCl. Complex 5 is readily converted to the eta(3)-allyl hydride complex Cp* Re(eta 3-C3H5)(CO)H by reaction with LiBEt3H, and to the phenyl or alkyl derivatives Cp* Re(eta(3)-C3H5)(CO)Ph or Cp* Re(eta(3)-C3H5)(CO)R by treatment with LiPh or Grignard reagents.

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页码：49 / 56

页数：8

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