ETA-3-ALLYL COMPLEXES OF TUNGSTEN .3. THE PREPARATION OF (ETA-5-C5H5)(ETA-3-C3H5)2(ETA-1-C3H5)W AND RELATED-COMPOUNDS

被引：5

作者：

AZEVEDO, MC ^{[1
]}

BROCK, TH ^{[1
]}

JOLLY, PW ^{[1
]}

RUFINSKA, A ^{[1
]}

SCHROTH, G ^{[1
]}

机构：

[1] MAX PLANCK INST COAL RES,W-4330 MULHEIM,GERMANY

来源：

POLYHEDRON | 1991年 / 10卷 / 4-5期

关键词：

D O I：

10.1016/S0277-5387(00)80212-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[(eta-3-C3H5)3WCl]2 reacts with substituted cyclopentadienyl alkali metal derivatives to give (eta-5-RC5H4)(eta-3-C3H5)2(eta-1-C3H5)W (where R is H, Me or t-C4H9). Analogous reactions involving indenyl- or fluorenyllithium produce (eta-5-L)(eta-3-C3H5)2W species.

引用

收藏

页码：459 / 462

页数：4

相关论文

共 7 条

[1] ETA-3-ALLYL COMPLEXES OF MOLYBDENUM .4. PREPARATION AND CRYSTAL-STRUCTURES OF SOME SUBSTITUTED-CYCLOPENTADIENYL MOLYBDENUM ALLYL DERIVATIVES [J].

ANDELL, O ;

GODDARD, R ;

HOLLE, S ;

JOLLY, PW ;

KRUGER, C ;

TSAY, YH .

POLYHEDRON, 1989, 8 (02) :203-209

[2] ETA-3-ALLYL COMPLEXES OF TUNGSTEN .2. REACTION OF [(ETA-3-C3H5)3WCL]2 WITH ORGANOMAGNESIUM COMPOUNDS [J].

BENN, R ;

BROCK, TH ;

JOLLY, PW ;

RUFINSKA, A ;

SCHROTH, G .

POLYHEDRON, 1990, 9 (01) :23-34

[3] FLUXIONAL BEHAVIOR IN ETA-3-ALLYL COMPLEXES OF CR, MO AND W AS SHOWN BY MAGNETIZATION TRANSFER DIFFERENCE SPECTROSCOPY (MTDS) [J].

BENN, R ;

RUFINSKA, A ;

SCHROTH, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 217 (01) :91-104

[4] ETA-3-ALLYL COMPLEXES OF TUNGSTEN .1. PREPARATION AND REACTIONS OF [(ETA-3-C3H5)3WCL]2 [J].

BENN, R ;

BROCK, TH ;

DIAS, MCFB ;

JOLLY, PW ;

RUFINSKA, A ;

SCHROTH, G ;

SEEVOGEL, K ;

WASSMUTH, B .

POLYHEDRON, 1990, 9 (01) :11-22

[5] ENTHALPIES OF FORMATION OF TI(ETA-C5H5)2(OR)2 COMPLEXES (R=C6H5, 2-CH3C6H4, 3-CH3C6H4, 4-CH3C6H4, AND 2-CLC6H4) [J].

DIAS, AR ;

SALEMA, MS ;

SIMOES, JAM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 222 (01) :69-78

[6] ETA-3-ALLYL COMPLEXES OF MOLYBDENUM - THE PREPARATION AND STRUCTURE OF [MO(ETA-3-C3H5)2(ETA-5-C5H5)] [J].

JOLLY, PW ;

KRUGER, C ;

ROMAO, CC ;

ROMAO, MJ .

ORGANOMETALLICS, 1984, 3 (06) :936-937

[7]

SKINNER HA, 1987, MOL STRUCTURE ENERGE, V2, P233