The Nature of Nitrogen-Modified Titanium Dioxide Photocatalysts Active in Visible Light

被引：331

作者：

Mitoraj, Dariusz ^{[1
]}

Kisch, Horst ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91058 Erlangen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 51期

关键词：

Fermi level; heterogeneous catalysis; photochemistry; semiconductors; titanium;

D O I：

10.1002/anie.200800304

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Can you see the light? Calcining a mixture of urea and TiO2 produces amino-tri-striazine derivatives covalently attached to TiO2 (see scheme). Therefore, the photocatalytic activity of this material in the visible range does not originate from surface defects or the presence of nitridic, amidic, or oxide species. This dye-sensitized titania efficiently photocatalyzes the oxidation of HCOOH to CO2 and H2O. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9975 / 9978

页数：4

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