Investigation of the interaction between a sulfonated azo dye (AO7) and a TiO2 surface

被引：150

作者：

Bauer, C

Jacques, P

Kalt, A

机构：

[1] Ecole Natl Super Chim, Lab Chim Text, F-68093 Mulhouse, France

[2] Ecole Natl Super Chim, CNRS, UMR 7525, Dept Photochim Gen, F-68093 Mulhouse, France

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 307卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(99)00518-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption of an azo dye, Acid Orange 7 (AO7), on a TiO2 surface was studied using FT-IR spectroscopy and adsorption isotherm parameters. The major FT-IR bands of the dye have been assigned in the range 1000-1900 cm(-1). Within the AO7-TiO2 complex, the dye appears to exist in its hydrazone form. The interaction of AO7 with the TiO2 surface is strong, leading to a surface inner-sphere-type complex. The dye is linked to three Ti-IV surface metallic cations through two oxygen atoms from the sulfonate group and the oxygen atom of the carbonyl group of the hydrazone tautomer. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：397 / 406

页数：10

共 36 条

[11] In situ infrared spectroscopic analysis of the adsorption of ruthenium(II) bipyridyl dicarboxylic acid photosensitisers to TiO2 in aqueous solutions [J].