Ion transport modelling through nanofiltration membranes

被引:72
作者
Garba, Y [1 ]
Taha, S [1 ]
Gondrexon, N [1 ]
Dorange, G [1 ]
机构
[1] Ecole Natl Super Chim Rennes, Lab Chim Eaux & Environm, F-35700 Rennes, France
关键词
nanofiltration; model; ion transfer parameters; transport mechanism; salt rejection;
D O I
10.1016/S0376-7388(99)00085-X
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The aim of this work is to study the transport mechanism of ions through nanofiltration membranes. A model based on extended Nernst-Planck and film theory equations is reported. This model can be characterized by three transport parameters: the water permeability L-p, the salt transmittance Phi and the effective salt transfer coefficient K-eff. The knowledge of the feed and permeate concentration and of the permeate volumetric flux enable us to calculate these transport parameters. The model is used to estimate cadmium salts rejection by a NANOMAX 50 membrane. Experimental and calculated results are shown to be in good agreement. The model is then successfully extended to experimental data reported in the literature. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:187 / 200
页数:14
相关论文
共 34 条
[11]  
MAUREL A, 1993, TECHNIQUE INGENIEUR, pJ2790
[12]   THEORETICAL MODIFICATION OF THE FINELY POROUS MODEL FOR REVERSE-OSMOSIS TRANSPORT [J].
MEHDIZADEH, H ;
DICKSON, JM .
JOURNAL OF APPLIED POLYMER SCIENCE, 1991, 42 (04) :1143-1154
[13]  
MERTEN U, 1966, TRANSPORT PROPERTIES
[14]  
NICOLAS S, 1992, THESIS U RENNESL
[15]   FOULING AND RETENTION OF NANOFILTRATION MEMBRANES [J].
NYSTROM, M ;
KAIPIA, L ;
LUQUE, S .
JOURNAL OF MEMBRANE SCIENCE, 1995, 98 (03) :249-262
[16]   INTERMEDIATE REVERSE-OSMOSIS ULTRAFILTRATION (RO UF) MEMBRANES FOR CONCENTRATION AND DESALTING OF LOW-MOLECULAR WEIGHT ORGANIC SOLUTES [J].
PERRY, M ;
LINDER, C .
DESALINATION, 1989, 71 (03) :233-245
[17]  
PONTALIER PY, 1995, GENIE PROCEDES, V9, P417
[18]  
PUSCH W, 1990, DESALINATION, V77, P35
[19]   SOME CONSIDERATIONS ON MASS-TRANSFER RESISTANCES IN SOLUTION DIFFUSION-TYPE MEMBRANE PROCESSES [J].
RAUTENBACH, R ;
HELMUS, FP .
JOURNAL OF MEMBRANE SCIENCE, 1994, 87 (1-2) :171-181
[20]   Investigation of ion separation by microporous nanofiltration membranes [J].
Rios, GM ;
Joulie, R ;
Sarrade, SJ ;
Carles, M .
AICHE JOURNAL, 1996, 42 (09) :2521-2528