Conductive polypyrrole and poly(allylamine hydrochloride) nanotubes fabricated with layer-by-layer assembly

被引:32
作者
Ai, SF [1 ]
He, Q [1 ]
Tao, C [1 ]
Zheng, SP [1 ]
Li, JB [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Key Lab Colloid Interface Sci,Int Joint Lab, Beijing 100080, Peoples R China
关键词
conductivity; nanotechnology; nanotubes; PC membrane template; polyelectrolytes;
D O I
10.1002/marc.200500590
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Conductive nanotubes were fabricated by the alternate adsorption of negatively charged polypyrrole (PPy) and positively charged poly(allylamine hydrochloride) (PAH) onto the inner pores of polycarbonate templates. Nanotubes are obtained by the subsequently removal of the template. Using several microscopic and spectroscopic techniques, we demonstrate that the yielded materials possess a tubular structure and conductive properties. The conductivity of PPy/PAH nanotubes is measured as 0.008 S center dot cm(-1).
引用
收藏
页码:1965 / 1969
页数:5
相关论文
共 43 条
[1]   Highly flexible polyelectrolyte nanotubes [J].
Ai, SF ;
Lu, G ;
He, Q ;
Li, JB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (37) :11140-11141
[2]   Synthesis and characterization of active ester-functionalized polypyrrole-silica nanoparticles: Application to the covalent attachment of proteins [J].
Azioune, A ;
Ben Slimane, A ;
Hamou, LA ;
Pleuvy, A ;
Chehimi, MM ;
Perruchot, C ;
Armes, SP .
LANGMUIR, 2004, 20 (08) :3350-3356
[3]   A water-soluble and self-doped conducting polypyrrole graft copolymer [J].
Bae, WJ ;
Kim, KH ;
Jo, WH ;
Park, YH .
MACROMOLECULES, 2005, 38 (04) :1044-1047
[4]   ELECTRONICALLY CONDUCTIVE POLYMER FIBERS WITH MESOSCOPIC DIAMETERS SHOW ENHANCED ELECTRONIC CONDUCTIVITIES [J].
CAI, ZH ;
MARTIN, CR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (11) :4138-4139
[5]   Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating [J].
Caruso, F ;
Caruso, RA ;
Möhwald, H .
SCIENCE, 1998, 282 (5391) :1111-1114
[6]   Fabrication of Ru and Ru-based functionalized nanotubes [J].
Chen, J ;
Tao, ZL ;
Li, SL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (10) :3060-3061
[7]   Molecular self-assembly of conducting polymers [J].
Cheung, J.H. ;
Fou, A.F. ;
Rubner, M.F. .
Thin Solid Films, 1994, 244 (1 -2 pt 3) :985-989
[8]   Surface modification of polycarbonate and poly(ethylene terephthalate) films and membranes by polyelectrolyte deposition [J].
Dauginet, L ;
Duwez, AS ;
Legras, R ;
Demoustier-Champagne, S .
LANGMUIR, 2001, 17 (13) :3952-3957
[9]   COLLOIDAL DISPERSIONS OF SURFACTANT-STABILIZED POLYPYRROLE PARTICLES [J].
DEARMITT, C ;
ARMES, SP .
LANGMUIR, 1993, 9 (03) :652-654
[10]   Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].
Decher, G .
SCIENCE, 1997, 277 (5330) :1232-1237