(eta 3-allyl)dicarbonyl(1,10-phenanthroline)-(trifluoroacetato)molybdenum, (I), and [syn(1,2,3-eta)-2-butenyl]dicarbonyl(1,10-phenanthroline)(trifluoroacetato)molybdenum, (II)

被引：13

作者：

Eriksson, L

Sjogren, MPT

Akermark, B

机构：

[1] ASTRA PROD CHEM AB,S-15185 SODERTALJE,SWEDEN

[2] ROYAL INST TECHNOL,DEPT ORGAN CHEM,S-10044 STOCKHOLM,SWEDEN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195009425

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This structure determination shows that in the two molybdenum complexes of the title, (I), [Mo(C2F3O2)(C3H5)(C12H8N2)(CO)2], and (II), [MO(C2F3O2)(C4H7)(C12H8N2)(CO)(2)], the phenanthroline ligand is perpendicular to the molybdenum-dicarbonyl plane. This is in contrast to similar molybdenum complexes, where the ligand is in the plane.

引用

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页码：77 / 80

页数：4

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