Chiral borromeates

被引：57

作者：

Pentecost, Cari D.

Peters, Andrea J.

Chichak, Kelly S.

Cave, Gareth W. V.

Cantrill, Stuart J.

Stoddart, J. Fraser

机构：

[1] Univ Calif Los Angeles, Calif Nanosyst Inst, Los Angeles, CA 90095 USA

[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

[3] Nottingham Trent Univ, Sch Biomed & Nat Sci, Nottingham NG11 8NS, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 25期

关键词：

chirality; Schiff bases; self-assembly; supramolecular chemistry; template synthesis;

D O I：

10.1002/anie.200600817

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The fellowship of the rings: Circular dichroism measurements reveal that chirality is transferred from 12 stereogenic centers to 6 octahedral zinc(II) centers (see picture) in two enantiomeric pairs of chiral Borromeates, one of which has been found to be wholly asymmetric in the solid state by X-ray crystallography. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4099 / 4104

页数：6

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