Tailoring of metal cluster-like materials for the molecular oxygen reduction reaction

被引：14

作者：

Alonso-Vante, Nicolas ^{[1
]}

机构：

[1] Univ Poitiers, CNRS, UMR 6503, Lab Electrocatalysis, F-86022 Poitiers, France

来源：

PURE AND APPLIED CHEMISTRY | 2008年 / 80卷 / 10期

关键词：

electrocatalyst; multi-electron charge transfer; acid solution; ruthenium; platinum; nanoalloys; nanomaterials;

D O I：

10.1351/pac200880102103

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Research of nanometer scale range catalysts based on cluster-like mono-, bimetallic, and chalcogenides for oxygen reduction reaction (ORR) as cathodes, a major challenge for polymer electrolyte membrane fuel cells (PEMFCs) nowadays, for facilitating, efficient electron transfer using the carbonyl chemical route is reviewed. A strategy aimed at reducing the amount of expensive catalyst materials, giving the accessibility of non-noble materials and taking into account the activity and selectivity of cathodes for the ORR is devised as well.

引用

收藏

页码：2103 / 2114

页数：12

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