Determination of the relative photodetachment cross sections of the two isomers of (H2O)(6)(-) using saturated photodetachment

被引:38
作者
Bailey, CG
Johnson, MA
机构
[1] Department of Chemistry, Sterling Chemistry Laboratory, Yale University, New Haven, CT 06520-8107
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0009-2614(96)01413-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report relative photodetachment cross sections for the two isomers of (H2O)(6)(-) at 1.165 eV by monitoring the photoelectron spectrum as a function of laser fluence. The cross sections of the two isomers differ by only about a factor of three, much closer to each other than suggested by recent calculations by Kim et al.
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页码:185 / 189
页数:5
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