Novel three-dimensional 3d-4f microporous magnets exhibiting selective gas adsorption behavior

被引：128

作者：

Li, Cui-Jin ^{[1
]}

Lin, Zhuo-jia ^{[1
]}

Peng, Meng-Xia ^{[1
,2
]}

Leng, Ji-Dong ^{[1
]}

Yang, Ming-Mei ^{[1
,3
]}

Tong, Ming-Liang ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China

[2] Jiaying Univ, Dept Chem, Meizhou 514015, Peoples R China

[3] Guangxi Teachers Educ Univ, Dept Chem, Nanning 530000, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 47期

关键词：

D O I：

10.1039/b815024a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three microporous Ln-Co-pyta heterometallic compounds [Ln(4)Co(3)(pyta)(6)(H2O)(9)]center dot 5H(2)O (Ln = Sm (1), Eu (2), Gd (3); H(3)pyta = 2,4,6-pyridinetricarboxylic acid) have interesting selective adsorption abilities towards H-2/N-2 and CO2/N-2 because of size-selective effects; magnetic analysis reveals that 3 has a ferromagnetic behavior.

引用

收藏

页码：6348 / 6350

页数：3

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