A quantum-mechanical study of the dynamics of the N(2D)+H2→NH+H reaction

被引：124

作者：

Honvault, P ^{[1
]}

Launay, JM ^{[1
]}

机构：

[1] Univ Rennes 1, PALMS, CNRS, UMR 6627, F-35042 Rennes, France

来源：

JOURNAL OF CHEMICAL PHYSICS | 1999年 / 111卷 / 15期

关键词：

D O I：

10.1063/1.480016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have studied the low energy quantum dynamics of the N(D-2) + H-2(X (1)Sigma(g)(+))--> NH(X (3)Sigma(-)) + H(S-2) reaction. We use the hyperspherical method and a recently published ab initio potential energy surface. We find a forward-backward symmetry in the differential cross sections which is characteristic of a complex formation. We also present rotational and vibrational integral cross sections. (C) 1999 American Institute of Physics. [S0021-9606(99)01239-8].

引用

页码：6665 / 6667

页数：3

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