Polyterpenes by ring opening metathesis polymerization of caryophyllene and humulene

被引：38

作者：

Grau, Etienne ^{[1
]}

Mecking, Stefan ^{[1
]}

机构：

[1] Univ Konstanz, Dept Chem, Chair Chem Mat Sci, D-78457 Constance, Germany

来源：

GREEN CHEMISTRY | 2013年 / 15卷 / 05期

关键词：

RENEWABLE RESOURCES; CHEMISTRY; CATALYSTS; ROMP;

D O I：

10.1039/c3gc40300a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ring opening metathesis polymerization of the natural sesquiterpenes caryophyllene and humulene, optionally complemented by exhaustive post-polymerization hydrogenation, yields non-crosslinked linear polymers with unprecedented microstructures reflecting the specific scaffolds of the feedstocks and with low glass transition temperatures in the range from -15 to -50 degrees C.

引用

页码：1112 / 1115

页数：4

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