Electrochemical actuator based on single-layer polypyrrole film

被引:46
作者
Han, GY
Shi, GQ [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
[2] Tsinghua Univ, Key Lab Bioorgan Phosphorus, Beijing 100084, Peoples R China
[3] Shanxi Univ, Inst Mol Sci, Chem Biol & Mol Engn Lab, Taiyuan 030006, Peoples R China
基金
中国国家自然科学基金;
关键词
polypyrrole; anisotropy film; actuator; high-performance;
D O I
10.1016/j.snb.2005.02.055
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Polypyrrole film with porous and compact zones in its vertical direction has been synthesized by direct oxidation of pyrrole in the mixed solvent of acetonitrile and dichloromethane contained a certain amount of anion surfactant of sodium 1,4-bis(2-ethylhexyl)sulfosuccinate (AOT). The actuator based on this single-layer film bends uniformly with the maximum bending angle much larger than 90 and has a fast response rate (similar to 60 s(-1) at 1.0 V versus SCE) and a long lifetime (> 20,000 cycles). The high performance of this actuator is mainly due to that the PPy film has a high conductivity and the actuator does not have delamination problem. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:259 / 264
页数:6
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