Molecular recognition in bisurea thermoplastic elastomers studied with pyrene-based fluorescent probes and atomic force microscopy

被引:26
作者
Botterhuis, Nicole E. [1 ]
Karthikeyan, S. [1 ]
Veldman, Dirk [1 ]
Meskers, Stefan C. J. [1 ]
Sijbesma, Rint P. [1 ]
机构
[1] Eindhoven Univ Technol, Dept Chem Engn, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands
关键词
D O I
10.1039/b804457k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fluorescence spectroscopy and atomic force microscopy (AFM) measurements using bisurea-pyrene probes show that they are randomly dispersed in the hard blocks of thermoplastic elastomers with matching bisurea groups, whereas they phase separate from polymers with non-matching or no bisurea groups.
引用
收藏
页码:3915 / 3917
页数:3
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