Post-Functionalization of Polymers via Orthogonal Ligation Chemistry

被引：177

作者：

Goldmann, Anja S. ^{[1
]}

Glassner, Mathias ^{[1
]}

Inglis, Andrew J. ^{[1
]}

Barner-Kowollik, Christopher ^{[1
]}

机构：

[1] Karlsruhe Inst Technol, Inst Tech Chem & Polymerchem, D-76131 Karlsruhe, Germany

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2013年 / 34卷 / 10期

关键词：

click chemistry; modular and orthogonal ligation; post-functionalization; polymers; DIELS-ALDER REACTION; OPENING METATHESIS POLYMERIZATION; TRANSFER RADICAL POLYMERIZATION; FREE CLICK CHEMISTRY; AZIDE-ALKYNE CYCLOADDITION; PALLADIUM-CATALYZED VINYLATION; CHAIN TRANSFER POLYMERIZATION; PHASE-TRANSFER CONDITIONS; DEFINED BLOCK-COPOLYMERS; ABC TRIBLOCK COPOLYMERS;

D O I：

10.1002/marc.201300017

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The establishment of advanced living/controlled polymerization protocols allows for engineering synthetic polymers in a precise fashion. Combining advanced living/controlled polymerization techniques with highly efficient coupling chemistries facilitates quantitative, modular, and orthogonal functionalization of synthetic polymer strands at their chain termini as well as side-chain functionalization. The review highlights the current status of selected post-functionalization techniques of polymers via orthogonal ligation chemistries, major characteristics of the specific transformation chemistry, as well as the characterization of the products.

引用

页码：810 / 849

页数：40

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