A transition metal-hydroperoxo complex stabilized by hydrogen-bonding interaction:: The first example of a hydroperoxopalladium species characterized by X-ray crystallography, (κ2-TpiPr)Pd(PPh3)(OOH) [TpiPr = hydrotris(3,5-diisopropylpyrazolyl)borato]

被引：22

作者：

Akita, M ^{[1
]}

Miyaji, T ^{[1
]}

Hikichi, S ^{[1
]}

Moro-oka, Y ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 08期

关键词：

D O I：

10.1246/cl.1999.813

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(kappa(2)-Tp(iPr))Pd(PPh3)-OOH, the first example of a structurally characterized hydroperoxopalladium species, contains hydrogen-bonding interaction between the OOH moiety and the noncoordinated pyrazolyl ring.

引用

页码：813 / 814

页数：2

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