Efficient Dye-Sensitized Photovoltaic Wires Based on an Organic Redox Electrolyte

被引：116

作者：

Pan, Shaowu ^{[1
,2
,3
]}

Yang, Zhibin ^{[1
,2
]}

Li, Houpu ^{[1
,2
]}

Qiu, Longbin ^{[1
,2
]}

Sun, Hao ^{[1
,2
]}

Peng, Huisheng ^{[1
,2
,3
]}

机构：

[1] Fudan Univ, Dept Macromol Sci, State Key Lab Mol Engn Polymers, Shanghai 200438, Peoples R China

[2] Fudan Univ, Adv Mat Lab, Shanghai 200438, Peoples R China

[3] Tongji Univ, Sch Mat Sci & Engn, Shanghai 201804, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 29期

关键词：

SOLAR-CELLS; COUNTER ELECTRODES; CARBON NANOTUBES; PERFORMANCE; COUPLE;

D O I：

10.1021/ja405012w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An organic thiolate/disulfide redox couple with low absorption in the visible region was developed for use in fabricating novel dye-sensitized photovoltaic wires with an aligned carbon nanotube (CNT) fiber as the counter electrode. These flexible wire devices achieved a maximal energy conversion efficiency of 7.33%, much higher than the value of 5.97% for the conventional I-/I-3(-) redox couple. In addition, the aligned CNT fiber also greatly outperforms the conventional Pt counter electrode with a maximal efficiency of 2.06% based on the thiolate/disulfide redox couple.

引用

页码：10622 / 10625

页数：4

共 29 条

[21]

Varghese OK, 2009, NAT NANOTECHNOL, V4, P592, DOI [10.1038/nnano.2009.226, 10.1038/NNANO.2009.226]

[22]

Wang MK, 2010, NAT CHEM, V2, P385, DOI [10.1038/NCHEM.610, 10.1038/nchem.610]

[23] Optical Fiber/Nanowire Hybrid Structures for Efficient Three-Dimensional Dye-Sensitized Solar Cells [J].

Weintraub, Benjamin ;

Wei, Yaguang ;

Wang, Zhong Lin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (47) :8981-8985

[24] Economical Pt-Free Catalysts for Counter Electrodes of Dye-Sensitized Solar Cells [J].

Wu, Mingxing ;

Lin, Xiao ;

Wang, Yudi ;

Wang, Liang ;

Guo, Wei ;

Qu, Daidi ;

Peng, Xiaojun ;

Hagfeldt, Anders ;

Graetzel, Michael ;

Ma, Tingli .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (07) :3419-3428

[25] Iodine/Iodide-Free Dye-Sensitized Solar Cells [J].

Yanagida, Shozo ;

Yu, Youhai ;

Manseki, Kazuhiro .

ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1827-1838

[26] Porphyrin-Sensitized Solar Cells with Cobalt (II/III)-Based Redox Electrolyte Exceed 12 Percent Efficiency [J].

Yella, Aswani ;

Lee, Hsuan-Wei ;

Tsao, Hoi Nok ;

Yi, Chenyi ;

Chandiran, Aravind Kumar ;

Nazeeruddin, Md. Khaja ;

Diau, Eric Wei-Guang ;

Yeh, Chen-Yu ;

Zakeeruddin, Shaik M. ;

Graetzel, Michael .

SCIENCE, 2011, 334 (6056) :629-634

[27] ZnO Nanostructures for Dye-Sensitized Solar Cells [J].

Zhang, Qifeng ;

Dandeneau, Christopher S. ;

Zhou, Xiaoyuan ;

Cao, Guozhong .

ADVANCED MATERIALS, 2009, 21 (41) :4087-4108

[28] Porous, Platinum Nanoparticle-Adsorbed Carbon Nanotube Yarns for Efficient Fiber Solar Cells [J].

Zhang, Sen ;

Ji, Chunyan ;

Bian, Zuqiang ;

Yu, Pingrong ;

Zhang, Luhui ;

Liu, Dianyi ;

Shi, Enzheng ;

Shang, Yuanyuan ;

Peng, Haitao ;

Cheng, Qiao ;

Wang, Dong ;

Huang, Chunhui ;

Cao, Anyuan .

ACS NANO, 2012, 6 (08) :7191-7198

[29] Enhanced charge-collection efficiencies and light scattering in dye-sensitized solar cells using oriented TiO2 nanotubes arrays [J].

Zhu, Kai ;

Neale, Nathan R. ;

Miedaner, Alexander ;

Frank, Arthur J. .

NANO LETTERS, 2007, 7 (01) :69-74

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