Biotransformation of (+)- and (-)-menthol by the larvae of common cutworm (Spodoptera litura)

被引：19

作者：

Miyazawa, M ^{[1
]}

Kumagae, S ^{[1
]}

Kameoka, H ^{[1
]}

机构：

[1] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Higashiosaka, Osaka 5778502, Japan

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1999年 / 47卷 / 09期

关键词：

common cutworm; Spodoptera litura; biotransformation; menthol; (+)-7-hydroxymenthol; (-)-7-hydroxymenthol;

D O I：

10.1021/jf980924u

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

(+)-Menthol was mixed in an artificial diet at a concentration of 1 mg/g of diet, and the diet was fed to the last instar larvae of common cutworm (Spodoptera litura). Metabolites were recovered from frass and analyzed spectroscopically. (+)-Menthol was transformed mainly to (+)-7-hydroxymenthol. Similarly, (-)-menthol was transformed mainly to (-)-7-hydroxymenthol. The C-7 position of (+)and (-)-menthol was preferentially oxidized.

引用

页码：3938 / 3940

页数：3

共 7 条

[1] BIOTRANSFORMATION OF MONOTERPENOIDS, (-)-MENTHOLS AND (+)-MENTHOLS, TERPINOLENE AND CARVOTANACETONE BY ASPERGILLUS SPECIES [J].

ASAKAWA, Y ;

TAKAHASHI, H ;

TOYOTA, M ;

NOMA, Y .

PHYTOCHEMISTRY, 1991, 30 (12) :3981-3987

[2]

FURUYA T, 1989, J CHEM SOC P1, V10, P1711

[3]

MADYASTHA KM, 1988, DRUG METAB DISPOS, V16, P765

[4] Biotransformation of alpha-terpinene in common cutworm larvae (Spodoptera litura Fabricius) [J].

Miyazawa, M ;

Wada, T ;

Kameoka, H .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1996, 44 (09) :2889-2893

[5] Biotransformation of (+)- and (-)-limonene by the larvae of common cutworm (Spodoptera litura) [J].

Miyazawa, M ;

Wada, T ;

Kameoka, H .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1998, 46 (01) :300-303

[6] STEREOSELECTIVITY IN OXIDATIVE AND REDUCTIVE TRANSFORMATIONS OF P-MENTHANE DERIVATIVES WITH THE CULTURED-CELLS OF NICOTIANA-TABACUM [J].

SUGA, T ;

HAMADA, H ;

HIRATA, T ;

IZUMI, S .

CHEMISTRY LETTERS, 1987, (05) :903-906

[7]

YUSHIMA K, 1991, REARING METHODS INSE, P214

← 1 →