A tetranuclear nickel(II) complex assembled from an asymmetric compartmental ligand and bearing an intramolecular [H3O2]2- bridge

被引：20

作者：

Adams, H ^{[1
]}

Clunas, S ^{[1
]}

Fenton, DE ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 05期

关键词：

D O I：

10.1039/b109019b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The asymmetric di-aminic compartmental ligand HL5 forms a tetranuclear nickel(II) complex in which the core is assembled from two confacial bioctahedra [Ni...Ni, similar to 2.90 Angstrom]; the open faces of the bioctahedra are joined at the O atoms of two mu-cresolato bridges [Ni...Ni, 3.72 Angstrom], and the shared faces of the bioctahedra are linked by a tetradentate (mu(4),eta(2))-perchlorate anion and by an unusual tetradentate (mu(4),eta(2))-[H3O2](-) bridge.

引用

页码：418 / 419

页数：2

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