Synthesis of monofunctionalised phthalocyanines using palladium catalysed cross-coupling reactions

被引:57
作者
Ali, H [1 ]
vanLier, JE [1 ]
机构
[1] UNIV SHERBROOKE,FAC MED,MRC,GRP RADIAT SCI,SHERBROOKE,PQ J1H 5N4,CANADA
关键词
D O I
10.1016/S0040-4039(97)00013-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The preparation of unsymmetrical monofunctionalised zinc phthalocyanines, using a palladium catalysed coupling reaction between zinc(II) tri(t-butyl)-4-iodophthalocyanine and a series of terminally substituted acetylenic derivatives, diethylvinyl phosphonate, methylacrylate (Heck Reactions), vinyltin derivatives (Stille reaction) and aryl boronated acids (Suzuki reaction), is described. (C) 1997, Elsevier Science Ltd.
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页码:1157 / 1160
页数:4
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