Tris(pentafluorophenyl) borane-containing electrolytes for electrochemical reversibility of lithium peroxide-based electrodes in lithium-oxygen batteries

被引：20

作者：

Choi, Nam-Soon ^{[1
]}

Jeong, Goojin ^{[2
]}

Koo, Bonjae ^{[1
]}

Lee, Yong-Won ^{[1
]}

Lee, Kyu Tae ^{[1
]}

机构：

[1] Ulsan Natl Inst Sci & Technol, Interdisciplinary Sch Green Energy, Ulsan 689798, South Korea

[2] Korea Elect Technol Inst, Adv Batteries Res Ctr, Songnam 463816, Gyeonggi, South Korea

来源：

JOURNAL OF POWER SOURCES | 2013年 / 225卷

基金：

新加坡国家研究基金会;

关键词：

Lithium-oxygen battery; Lithium peroxide; Electrolyte; Tris(pentafluorophenyl) borane; Solid electrolyte interphase; ANION RECEPTOR; AIR BATTERIES; LI-AIR; PERFORMANCE;

D O I：

10.1016/j.jpowsour.2012.10.029

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Tris(pentafluorophenyl) borane (TPFPB) is evaluated as an additive for improving electrochemical performance of lithium peroxide (Li2O2)-based electrodes. It is found that TPFPB significantly reduced the charge potential of Li2O2-based electrodes during the first charge process and improved reversible capacity during cycling without adding air (or O-2) to the cell. To confirm the effect of TPFPB on electrolyte decomposition, the surface chemistry of Li2O2-based electrodes cycled in electrolytes with and without TPFPB was investigated. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：95 / 100

页数：6