Conversion of a Bi nanowire array to an array of Bi-Bi2O3 core-shell nanowires and Bi2O3 nanotubes

被引:214
作者
Li, L [1 ]
Yang, YW [1 ]
Li, GH [1 ]
Zhang, LD [1 ]
机构
[1] Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, Key Lab Mat Phys, Hefei 230031, Peoples R China
关键词
bismuth; core-shell materials; nanotubes; nanowires; template synthesis;
D O I
10.1002/smll.200500382
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A template-based heat-treatment method has been developed to convert metal nanowire arrays into arrays of metal-metal oxide core-shell nanowires and single-crystalline metal oxide nanotubes. This process is. demonstrated by kinetically controlling the conversion of single-crystalline Bi nanowires to Bi-Bi2O3 core-shell nanowires via a multistep, slow oxidation method, and then controlling their further conversion to a single-crystalline Bi2O3 nanotube array via fast oxidation. This process can conveniently be extended to fabricate a free-standing, easily oxidized metal-metal oxide nanowire and metal oxide nanotube array, which may have,future applications in nanoscale optics, electronics, and magnetics.
引用
收藏
页码:548 / 553
页数:6
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