A General Strategy for Synthesizing Cubeoctameric Silsesquioxanes Containing Polymerizable Functional Groups

被引：5

作者：

Feher, Frank J. ^{[1
]}

Schwab, Joseph J. ^{[1
]}

Tellers, David M. ^{[1
]}

Burstein, Aaron ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

MAIN GROUP CHEMISTRY | 1998年 / 2卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1080/10241229812331341329

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general method has been developed for the preparation of silsesquioxanes with potentially polymerizable p,p'-disubstituted diphenylmethyl groups attached to one vertex of the "T(8)" framework, including [Cy(7)Si(8)O(12)(CH(2))(4)CH(C(6)H(4)OH)(2)],((9a) under bar), [Cy(7)Si(8)O(12)(CH(2))(10)CH-C(6)H(4)OH)(2)] ((9b) under bar), [Cy(7)Si(8)O(12)(CH(2))(4)CH(C(6)H(4)NH(2))(2)] ((10a) under bar), [Cy(7)Si(8)O(12)(CH(2))(10)CH(C(6)H(4)NH(2))(2)]((10b) under bar), [Cy(7)Si(8)O(12)(CH(2))(4)CH(C(6)H(4)CO(2)H)(2) ((14) under bar). The reaction of [Cy(7)Si(8)O(12)CH(2)CH(2)CO(2)CH(3)] ((2) under bar) with BrMgC(6)H(4)OCH(2)Ph ((6a) under bar) affords an interesting disilanol derived from the hydrolytic cleavage of one Si-O-Si linkage in a completely condensed T(8) framework.

引用

页码：169 / 181

页数：13

共 38 条

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