Derivatisation of octasilsesquioxane with alcohols and silanols

被引：36

作者：

Bassindale, AR

Gentle, T

机构：

[1] Chemistry Department, Open University, Walton Hall

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 521卷 / 1-2期

关键词：

silicon; octasilsesquioxane; dendrimers; hydrosilylation;

D O I：

10.1016/0022-328X(96)06322-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The T-8 cage in (HSiO3/2)(8) has been successfully derivatised to give (ROSiO(3/2))(8) and (R(3)SiOSiO(3/2))(8) by the reaction with alcohols and silanols in the presence of catalytic amounts of amines. The most effective catalyst is Et(2)NOH.

引用

页码：391 / 393

页数：3

共 11 条

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