Comparison of different advanced oxidation processes for phenol degradation

被引:953
作者
Esplugas, S [1 ]
Giménez, J [1 ]
Contreras, S [1 ]
Pascual, E [1 ]
Rodríguez, M [1 ]
机构
[1] Univ Barcelona, Dept Ingn Quim & Met, E-08028 Barcelona, Spain
关键词
phenol; ozone; UV radiation; hydrogen peroxide; Fenton; photocatalysis;
D O I
10.1016/S0043-1354(01)00301-3
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
xAdvanced Oxidation Processes (O-3, O-3/H2O2, UV, UV/O-3, UV/H2O2, O-3/UV/H2O2, Fe2+ /H2O2 and photocatalysis) for degradation of phenol in aqueous solution have been studied in earlier works. In this paper, a comparison of these techniques is undertaken: pH influence, kinetic constants, stoichiometric coefficient and optimum oxidant/pollutant ratio. Of the tested processes, Fenton reagent was found to the fastest one for phenol degradation. However. lower costs were obtained with ozonation. In the ozone combinations, the best results were achieved with single ozonation. As for the UV processes, UV/H2O2 showed the highest degradation rate. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1034 / 1042
页数:9
相关论文
共 29 条
[1]   OXIDATION AND BIODEGRADABILITY ENHANCEMENT OF 1,4-DIOXANE USING HYDROGEN-PEROXIDE AND OZONE [J].
ADAMS, CD ;
SCANLAN, PA ;
SECRIST, ND .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1994, 28 (11) :1812-1818
[2]   Advanced oxidation processes (AOP) for water purification and recovery [J].
Andreozzi, R ;
Caprio, V ;
Insola, A ;
Marotta, R .
CATALYSIS TODAY, 1999, 53 (01) :51-59
[3]  
[Anonymous], 1997, RRD PHOTOCHEM PHOTOB
[4]   Nitroaromatic hydrocarbon ozonation in water. 2. Combined ozonation with hydrogen peroxide or UV radiation [J].
Beltran, FJ ;
Encinar, JM ;
Alonso, MA .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (01) :32-40
[5]   Chemical decomposition of 2,4,6-trichlorophenol by ozone, Fenton's reagent, and UV radiation [J].
Benitez, FJ ;
Beltran-Heredia, J ;
Acero, JL ;
Rubio, FJ .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1999, 38 (04) :1341-1349
[6]  
Bigda RJ, 1995, CHEM ENG PROG, V91, P62
[7]   New evidence against hydroxyl radicals as reactive intermediates in the thermal and photochemically enhanced fenton reactions [J].
Bossmann, SH ;
Oliveros, E ;
Göb, S ;
Siegwart, S ;
Dahlen, EP ;
Payawan, L ;
Straub, M ;
Wörner, M ;
Braun, AM .
JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (28) :5542-5550
[8]  
CHAMARRO E, 1996, QUIM IND, V1, P28
[9]   Photocatalytic degradation of phenol: Comparison between pilot-plant-scale and laboratory results [J].
Curco, D ;
Malato, S ;
Blanco, J ;
Gimenez, J ;
Marco, P .
SOLAR ENERGY, 1996, 56 (05) :387-400
[10]   Reactor modelling in the photocatalytic oxidation of wastewater [J].
Gimenez, J ;
Curco, D ;
Marco, P .
WATER SCIENCE AND TECHNOLOGY, 1997, 35 (04) :207-213