New erythrolides from the Caribbean gorgonian octocoral Erythropodium caribaeorum

被引:11
作者
Banjoo, D
Mootoo, BS [1 ]
Ramsewak, RS
Sharma, R
Lough, AJ
McLean, S
Reynolds, WF
机构
[1] Univ W Indies, Dept Chem, St Augustine, Trinidad Tobago
[2] Univ Toronto, Dept Chem, Toronto, ON M5S 1A1, Canada
来源
JOURNAL OF NATURAL PRODUCTS | 2002年 / 65卷 / 03期
关键词
D O I
10.1021/np010333p
中图分类号
Q94 [植物学];
学科分类号
071001 ;
摘要
Seven new briarane diterpenes, erythrolides K-Q (1-7), as well as the known compounds erythrolides A, B, C, F, and J have been isolated from samples of the Caribbean gorgonian Erythropodium caribaeorum, collected at Buccoo Reef and Flying Reef, Tobago. The structures of the new compounds were determined by high-resolution H-1 and C-13 NMR spectroscopy utilizing COSY, HMBC, HMQC, and NOESY experiments. The structures of erythrolides K and P were confirmed and their relative stereochemistry determined by X-ray crystallographic analysis.
引用
收藏
页码:314 / 318
页数:5
相关论文
共 9 条
[1]   An unusual erythrolide containing a bicycle [9.2.1.] tetradecane skeleton [J].
Banjoo, D ;
Maxwell, AR ;
Mootoo, BS ;
Lough, AJ ;
McLean, S ;
Reynolds, WF .
TETRAHEDRON LETTERS, 1998, 39 (12) :1469-1472
[2]   DITERPENES FROM THE GORGONIAN CORAL ERYTHROPODIUM-CARIBAEORUM FROM THE SOUTHERN CARIBBEAN [J].
DOOKRAN, R ;
MAHARAJ, D ;
MOOTOO, BS ;
RAMSEWAK, R ;
MCLEAN, S ;
REYNOLDS, WF ;
TINTO, WF .
JOURNAL OF NATURAL PRODUCTS, 1993, 56 (07) :1051-1056
[3]   ERYTHROLIDES - UNIQUE MARINE DITERPENOIDS INTERRELATED BY A NATURALLY-OCCURRING DI-PI-METHANE REARRANGEMENT [J].
LOOK, SA ;
FENICAL, W ;
VANENGEN, D ;
CLARDY, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (17) :5026-5027
[4]   Briarane diterpenes from the gorgonian octocoral Erythropodium caribaeorum from the northern Caribbean [J].
Maharaj, D ;
Pascoe, KO ;
Tinto, WF .
JOURNAL OF NATURAL PRODUCTS, 1999, 62 (02) :313-314
[5]   Three novel monotetrahydrofuran annonaceous acetogenins from Annona montana [J].
Mootoo, BS ;
Ali, A ;
Khan, A ;
Reynolds, WF ;
McLean, S .
JOURNAL OF NATURAL PRODUCTS, 2000, 63 (06) :807-811
[6]   ERYTHRODIENE - A NEW SPIROBICYCLIC SESQUITERPENE OF A RARE SKELETAL CLASS FROM THE CARIBBEAN GORGONIAN CORAL ERYTHROPODIUM-CARIBAEORUM [J].
PATHIRANA, C ;
FENICAL, W ;
CORCORAN, E ;
CLARDY, J .
TETRAHEDRON LETTERS, 1993, 34 (21) :3371-3372
[7]   NEW BRIAREIN DITERPENES FROM THE CARIBBEAN GORGONIANS ERYTHROPODIUM-CARIBAEORUM AND BRIAREUM SP [J].
PORDESIMO, EO ;
SCHMITZ, FJ ;
CIERESZKO, LS ;
HOSSAIN, MB ;
VANDERHELM, D .
JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (07) :2344-2357
[8]   Briareins C-L, 10 new briarane diterpenoids from the common Caribbean gorgonian Briareum asbestinum [J].
Rodriguez, AD ;
Ramirez, C ;
Cobar, OM .
JOURNAL OF NATURAL PRODUCTS, 1996, 59 (01) :15-22
[9]   SOME DITERPENES FROM THE SEA PEN STYLATULA-SP [J].
WRATTEN, SJ ;
FAULKNER, DJ .
TETRAHEDRON, 1979, 35 (16) :1907-1912