A facile approach toward transition metal oxide hierarchical structures and their lithium storage properties

被引:60
作者
Zhang, Cuimiao [1 ,2 ]
Chen, Jing [1 ]
Zeng, Yi [1 ]
Rui, Xianhong [1 ,3 ]
Zhu, Jixin [1 ]
Zhang, Wenyu [1 ]
Xu, Chen [1 ]
Lim, Tuti Mariana [3 ,4 ]
Huey Hoon Hng [1 ]
Yan, Qingyu [1 ,5 ,6 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
[2] Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China
[3] Nanyang Technol Univ, Sch Civil & Environm Engn, Singapore 639798, Singapore
[4] Ngee Ann Polytech, Sch Life Sci & Chem Technol, Singapore 599489, Singapore
[5] Nanyang Technol Univ, Energy Res Inst, Singapore 637459, Singapore
[6] Nanyang Technol Univ, TUM CREATE Ctr Electromobil, Singapore 637459, Singapore
关键词
ELECTROCHEMICAL DEPOSITION; ANODE MATERIALS; HOLLOW SPHERES; CO3O4; ELECTRODE; CAPACITY; NANOSTRUCTURES; NANOCRYSTALS; SHEETS; ARRAYS;
D O I
10.1039/c2nr30525a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple, non-template, non-surfactant and environmentally friendly hydrothermal method is presented based on the controlled release of the reactants into the reaction solvents to induce slow nucleation and growth of three-dimensional hierarchical nanostructures of transition metal oxides. This method is a general approach, which can be used to prepare Co3O4, CuO, and Ni(OH)(2)/NiO. These metal oxides with hierarchical nanostructures can be used as anode materials for lithium-ion batteries with good Li storage performance, e. g. high specific capacities and stable cyclability.
引用
收藏
页码:3718 / 3724
页数:7
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