A facile approach toward transition metal oxide hierarchical structures and their lithium storage properties

被引:60
作者
Zhang, Cuimiao [1 ,2 ]
Chen, Jing [1 ]
Zeng, Yi [1 ]
Rui, Xianhong [1 ,3 ]
Zhu, Jixin [1 ]
Zhang, Wenyu [1 ]
Xu, Chen [1 ]
Lim, Tuti Mariana [3 ,4 ]
Huey Hoon Hng [1 ]
Yan, Qingyu [1 ,5 ,6 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
[2] Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China
[3] Nanyang Technol Univ, Sch Civil & Environm Engn, Singapore 639798, Singapore
[4] Ngee Ann Polytech, Sch Life Sci & Chem Technol, Singapore 599489, Singapore
[5] Nanyang Technol Univ, Energy Res Inst, Singapore 637459, Singapore
[6] Nanyang Technol Univ, TUM CREATE Ctr Electromobil, Singapore 637459, Singapore
关键词
ELECTROCHEMICAL DEPOSITION; ANODE MATERIALS; HOLLOW SPHERES; CO3O4; ELECTRODE; CAPACITY; NANOSTRUCTURES; NANOCRYSTALS; SHEETS; ARRAYS;
D O I
10.1039/c2nr30525a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple, non-template, non-surfactant and environmentally friendly hydrothermal method is presented based on the controlled release of the reactants into the reaction solvents to induce slow nucleation and growth of three-dimensional hierarchical nanostructures of transition metal oxides. This method is a general approach, which can be used to prepare Co3O4, CuO, and Ni(OH)(2)/NiO. These metal oxides with hierarchical nanostructures can be used as anode materials for lithium-ion batteries with good Li storage performance, e. g. high specific capacities and stable cyclability.
引用
收藏
页码:3718 / 3724
页数:7
相关论文
共 53 条
[31]   Self-Assembled Hierarchical MoO2/Graphene Nanoarchitectures and Their Application as a High-Performance Anode Material for Lithium-Ion Batteries [J].
Sun, Yongming ;
Hu, Xianluo ;
Luo, Wei ;
Huang, Yunhui .
ACS NANO, 2011, 5 (09) :7100-7107
[32]   Shape control of colloidal metal nanocrystals [J].
Tao, Andrea R. ;
Habas, Susan ;
Yang, Peidong .
SMALL, 2008, 4 (03) :310-325
[33]   Issues and challenges facing rechargeable lithium batteries [J].
Tarascon, JM ;
Armand, M .
NATURE, 2001, 414 (6861) :359-367
[34]   Quasiemulsion-Templated Formation of α-Fe2O3 Hollow Spheres with Enhanced Lithium Storage Properties [J].
Wang, Bao ;
Chen, Jun Song ;
Wu, Hao Bin ;
Wang, Zhiyu ;
Lou, Xiong Wen .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (43) :17146-17148
[35]   Investigation of cobalt oxides as anode materials for Li-ion batteries [J].
Wang, GX ;
Chen, Y ;
Konstantinov, K ;
Lindsay, M ;
Liu, HK ;
Dou, SX .
JOURNAL OF POWER SOURCES, 2002, 109 (01) :142-147
[36]   Synthesis and Lithium Storage Properties of Co3O4 Nanosheet-Assembled Multishelled Hollow Spheres [J].
Wang, Xi ;
Wu, Xing-Long ;
Guo, Yu-Guo ;
Zhong, Yeteng ;
Cao, Xinqiang ;
Ma, Ying ;
Yao, Jiannian .
ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (10) :1680-1686
[37]   NiO nanocone array electrode with high capacity and rate capability for Li-ion batteries [J].
Wang, Xinghui ;
Yang, Zhibo ;
Sun, Xiaolei ;
Li, Xiuwan ;
Wang, Desheng ;
Wang, Peng ;
He, Deyan .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (27) :9988-9990
[38]   Nanostructured NiO electrode for high rate Li-ion batteries [J].
Wang, Xinghui ;
Li, Xiuwan ;
Sun, Xiaolei ;
Li, Fei ;
Liu, Qiming ;
Wang, Qi ;
He, Deyan .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (11) :3571-3573
[39]   Beyond molecules: Self-assembly of mesoscopic and macroscopic components [J].
Whitesides, GM ;
Boncheva, M .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :4769-4774
[40]   Lithium Iron Borates as High-Capacity Battery Electrodes [J].
Yamada, Atsuo ;
Iwane, Nobuyuki ;
Harada, Yu ;
Nishimura, Shin-ichi ;
Koyama, Yukinori ;
Tanaka, Isao .
ADVANCED MATERIALS, 2010, 22 (32) :3583-+