Synthesis of different ring-size heterocycles from the same propargyl alcohol derivative by ligand effect on Pd(0)

被引：65

作者：

Kozawa, Y ^{[1
]}

Mori, M ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Pharmaceut Sci, Kita Ku, Sapporo, Hokkaido 0600812, Japan

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 08期

关键词：

allenylpalladium complex; eta(3)-propargylpalladium complex; hetercycles; pi-allylpalladium complex; DPPF;

D O I：

10.1016/S0040-4039(02)00043-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The type of ligand oil in an allenylpalladium complex, which was prepared from propargyl alcohol derivative and Pd(0), plays an important role in determination of the ring size of the cyclized compound. An intermediary palladium complex bearing a monodentate ligand gave a cyclized compound via palladacycle, while that bearing a bidentate ligand gave one-carbon elongated cyclized compound via a eta(3)-propargylalladium complex. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1499 / 1502

页数：4

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