Solid oxide fuel cell membranes supported by nickel grid anode

被引:51
作者
Rey-Mermet, Samuel [1 ]
Muralt, Paul [1 ]
机构
[1] Ecole Polytech Fed Lausanne, STI IMX Lab Ceram, CH-1015 Lausanne, Switzerland
关键词
microfabrication; thin film; nickel grid; silicon substrate; YSZ;
D O I
10.1016/j.ssi.2008.01.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Microfabricated solid oxide fuel cells (SOFC) have been integrated onto silicon substrates. The SOFC membrane contained a sputter deposited 8YSZ electrolyte layer with a thickness of 750 nm. It is supported on the anode side by a nickel grid grown by electroplating. The grid has either a hexagonal or a spiderweb pattern with maximal free standing length of 80 gm and a height comprised between 4 and 6 gm. The SOFC membranes have diameter up to 5 mm and are mechanically stable up to 550 degrees C. Completed with porous platinum anode and cathode, they show a maximal open circuit voltage (OCV) of 280 mV at 450 degrees C, under a mixture Of H-2 and Ar at the anode. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1497 / 1500
页数:4
相关论文
共 14 条
[1]   Fabrication and structural characterization of self-supporting electrolyte membranes for a micro solid-oxide fuel cell [J].
Baertsch, CD ;
Jensen, KF ;
Hertz, JL ;
Tuller, HL ;
Vengallatore, ST ;
Spearing, SM ;
Schmidt, MA .
JOURNAL OF MATERIALS RESEARCH, 2004, 19 (09) :2604-2615
[2]   Spray pyrolysis of La0.6Sr0.4Co0.2Fe0.8O3-δ thin film cathodes [J].
Beckel, D ;
Dubach, A ;
Studart, AR ;
Gauckler, LJ .
JOURNAL OF ELECTROCERAMICS, 2006, 16 (03) :221-228
[3]   Thin-film heterostructure solid oxide fuel cells [J].
Chen, X ;
Wu, NJ ;
Smith, L ;
Ignatiev, A .
APPLIED PHYSICS LETTERS, 2004, 84 (14) :2700-2702
[4]   High-performance ultrathin solid oxide fuel cells for low-temperature operation [J].
Huang, Hong ;
Nakamura, Masafumi ;
Su, Peichen ;
Fasching, Rainer ;
Saito, Yuji ;
Prinz, Fritz B. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (01) :B20-B24
[5]  
JANKOWSKI AF, 2002, P MAT RES S
[6]   A review of anode materials development in solid oxide fuel cells [J].
Jiang, SP ;
Chan, SH .
JOURNAL OF MATERIALS SCIENCE, 2004, 39 (14) :4405-4439
[7]   Thin-film solid oxide fuel cells on porous nickel substrates with multistage nanohole array [J].
Kang, S ;
Su, PC ;
Park, YI ;
Saito, Y ;
Prinz, FB .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (03) :A554-A559
[8]   Micro-fuel cell power sources [J].
Morse, Jeffrey D. .
INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2007, 31 (6-7) :576-602
[9]   Thin-film SOFCs using gastight YSZ thin films on nanoporous substrates [J].
Park, YI ;
Su, PC ;
Cha, SW ;
Saito, Y ;
Prinz, FB .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (02) :A431-A436
[10]  
REYMERMET S, 2006, Patent No. 2006069688